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Europe / Middle East / Africa / India: Refrigeration > Products > Refrigerants > KLEA®134a > KLEA®134a Physical Properties

REFRIGERATION


Physical Properties

Property Units Value
Molecular Weight   102.03
Boiling Point °C @ 1 atm -26.074
Melting Point °C -103
Critical Temparature °C 101.03
Critical Pressure bar 40.56
Critical Density kg/m3 508
Vapour Pressure (25°C) bar 6.652
Latent Heat of Vaporisation at nBpt kJ/kg 216.77
Saturated Vapour Density at nBpt kg/m3 5.229
Coeff. Vol. Therm. Exp. (LIQ,0-20°C) °C-1 0.002766
Speed of Sound (sat. LIQ)(25°C) m/sec 503
Adiabatic Exponent (VAP)(25°C/2.9bar)   1.142
Acentric Factor   0.3270
Dielectric Constant (VAP 25°C/1atm)   1.014
Dielectric Strength (R12=1)   0.5
Specific Resistivity (LIQ) AC Mohm.cm 180
Specific Resistivity (LIQ) DC Mohm.cm 66000
Purity % WT   99.98
Solubility In Water (20°C/1atm) % wt 0.0773

EQUATION OF STATE (MARTIN-HOU)


where : Tr = T/Tc, Pr = P/Pc, Vr = V/Vc = V.RHOc
X = 3.818866
B = 0.154030007
K = 7.479441939181823
Tc,Pc,RHOc = 374.18(K), 40.56(bar), 508.00(kg/m3)

A1,B1,C1 = -10.6756547802, 5.21550874265, -531.021431657
A2,B2,C2 = 12.3296910242, -7.4900230467, -1021.1029703
A3,B3,C3 = -9.88578225598, 6.9362804137, 2523.40618122
A4,B4,C4 = 2.814138511, -2.03421178211, -1020.8091303

EXTENDED ANTOINE EQUATION
              B
Ln(P) = A + ----- + DT + ELn(T)
C + T
  P = Vapour pressure bara
  T = Temperature K
  A = 102.5338784
  B = -5238.8786
  C = 0
  D = 0.02398227
  E = -15.8343842

LATENT HEAT VAPORISATION

  DHvap = A + Bx + Cx2 + Dx3 + Ex4
  where x = (1-(T/Tc))(1/3)

  A = 0 T = Temperature K
  B = 163.7313 Tc = Crit. Temperature K
  C = 460.3925  
  D = -510.952 DHvap kJ/kg
  E = 219.1886  

IDEAL GAS HEAT CAPACITY

Cp(ideal) = A + BT + CT2 + DT3 + E/T2

  A = 0.1345064 T = Temperature K
  B = 0.003258432  
  C = -4.2343E-06 Cp(ideal) kJ/kg.K
  D = 3.8408E0-9  
  E = -1.370898  

SATURATED LIQUID ENTHALPY

  H liq = A + Bx + Cx2 + Dx3 + Ex4
  where x = (1-(T/Tc))(1/3)

  A = 249.0896 T = Temperature K
  B = 189.8021 Tc = Crit. Temperature K
  C = -753.47 H liq kJ/kg
  D = 261.1633  
  E = -157.687  

LIQUID DENSITY

  d liq = A + Bx + Cx2 + Dx3 + Ex4
  where x = (1-(T/Tc))(1/3)

  A = 508 T = Temperature K
  B = 967.57693 Tc = Crit. Temperature K
  C = 298.02172 d liq kg/m3
  D = 79.877831  
  E = 89.838713  

LIQUID VISCOSITY

Ln(μ) liq = A + B/T + C/T2 + D/T3

  A = -9.707292 T = Temperature K
  B = 1140.7291 μ liq cP
  C = 0.0282451  
  D = -4.6720E-05  

LIQUID THERMAL CONDUCTIVITY

  K liq = A + BT + CT2 + DT3
  where x = (1-(T/Tc))(1/3)

  A = 0.295701 T = Temperature K
  B = -0.001285 Tc = Crit. Temperature K
  C = 2.7941E-06 K liq W/m.K
  D = -2.9630E-09  

SURFACE TENSION


σ = A(1-(T/Tc))1.26

  A =
60.21747
T = Temperature K
        Tc = Crit. Temperature K
        σ mN/m

SATURATED VAPOUR DENSITY

  d vap = A + Bx + C2 + Dx3 + Ex4
  where x = (1-(T/Tc))(1/3)

      For T=-50 TO 0°C  
  A = -113.501 T = Temperature K
  B = 3335.18 Tc = Crit. Temperature K
  C = -11368.8 d vap kg/m3
  D = 13688.75  
  E = -5583.8  
         
      For T= 0°C TO +80°C  
  A = 388.752  
  B = 84.07428  
  C = -3500.71  
  D = 5252.284  
  E = -2202.55  

IDEAL GAS VISCOSITY

μ ig = A + BT

  A = 0.000720275 T = Temperature K
  B = 0.000037581 μ ig cP

VAPOUR VISCOSITY (SATURATED VAPOUR)

μ vap = A + BT + CT2 + DT3

  A = -0.32671694 T = Temperature K
  B = 0.003456914 μ vap cP
  C = -1.1836E-05  
  D = 1.3599E-08  

IDEAL GAS THERMAL CONDUCTIVITY

Kig = A + BT

  A = -0.011484 T = Temperature K
  B = 0.000083646 Kig W/m.K

VAPOUR THERMAL CONDUCTIVITY (SATURATED VAPOUR)


Kgas = A + BT + CT2 + DT3

  A = -0.52938315 T = Temperature K
  B = 0.005516987 Kgas W/m.K
  C = -1.8908E-05  
  D = 2.1859E-08  

VAPOUR SPEED OF SOUND (SATURATED VAPOUR)

μ = A + BT + CT2 + DT3 + E/T

  A = 1815.1584 T = Temperature K
  B = -10.48764 μ m/s
  C = 0.03071408  
  D = -3.4566E-05  
  E = -106745.3

Temp (°C) LIQUID ENTH (kJ/kg) LATENT HEAT (kJ/kg) SAT VAP ENTH (kJ/kg) LIQUID Cp (J/g.K) ID. GAS Cp (J/g.K)
-50.00 36.22 231.60 267.82 1.2242 0.6934
-40.00 48.55 225.59 274.14 1.2423 0.7127
-30.00 61.07 219.31 280.38 1.2623 0.7316
-20.00 73.80 212.73 286.53 1.2846 0.7503
-10.00 86.77 205.79 292.56 1.3094 0.7687
0.00 100.00 198.44 298.45 1.3375 0.7869
10.00 113.53 190.61 304.15 1.3694 0.8048
20.00 127.41 182.20 309.61 1.4061 0.8226
25.00 134.49 177.74 312.23 1.4266 0.8314
30.00 141.67 173.09 314.76 1.4489 0.8402
40.00 156.41 163.09 319.50 1.4996 0.8576
50.00 171.70 151.96 323.67 1.5611 0.8749
60.00 187.68 139.52 327.00 1.6376 0.8921
70.00 204.53 124.51 329.03 1.7364 0.9092
80.00 222.52 106.27 328.79 1.8695 0.9263

Temp (°C) VAPOUR PRESS (bara) LIQUID DENSITY (kg/m3) LIQUID VISCOSITY (cP) LIQ. THERM COND (W/m.K) SURF TENSION (mN/m)
-50.00 0.295 1445 0.54 0.115 19.2
-40.00 0.512 1417 0.46 0.110 17.6
-30.00 0.844 1388 0.40 0.106 16.1
-20.00 1.327 1358 0.35 0.101 14.5
-10.00 2.005 1327 0.31 0.097 13.0
0.00 2.927 1295 0.27 0.093 11.6
10.00 4.144 1261 0.24 0.089 10.1
20.00 5.715 1225 0.21 0.084 8.76
25.00 6.652 1207 0.20 0.082 8.09
30.00 7.701 1187 0.19 0.080 7.42
40.00 10.167 1147 0.17 0.076 6.13
50.00 13.183 1102 0.15 0.072 4.89
60.00 16.824 1053 0.13 0.068 3.72
70.00 21.170 996 0.11 0.064 2.61
80.00 26.308 929 0.10 0.060 1.60

Temp (°C) SAT VAP DENSITY (kg/m3) ID. GAS VISCOSITY (Cp) SAT VAP VISCOSITY (cP) ID. GAS THERM COND (W/m.K) SAT VAP THERM COND (W/m.K) SPEED OF SOUND (m/s)
-50.00 1.650 0.0091 - 0.0072 - 141.8
-40.00 2.767 0.0095 - 0.0080 - 143.6
-30.00 4.426 0.0099 - 0.0089 - 145.0
-20.00 6.787 0.0102 0.0105 0.0097 0.0101 146.1
-10.00 10.04 0.0106 0.0112 0.0105 0.0114 146.7
0.00 14.43 0.0110 0.0116 0.0114 0.0123 146.8
10.00 20.22 0.0114 0.0119 0.0122 0.0130 146.4
20.00 27.77 0.0117 0.0121 0.0130 0.0137 145.2
25.00 32.34 0.0119 0.0122 0.0135 0.0140 144.4
30.00 37.51 0.0121 0.0124 0.0139 0.0144 143.3
40.00 50.00 0.0125 0.0127 0.0147 0.0153 140.5
50.00 66.20 0.0129 0.0133 0.0155 0.0165 136.7
60.00 87.33 0.0132 0.0141 0.0164 0.0182 131.6
70.00 115.61 0.0136 0.0153 0.0172 0.0205 125.2
80.00 155.09 0.0140 0.0169 0.0181 0.0235 117.3

The correlations in this data sheet should not be used outside the applicable ranges quoted. Contact Mexichem Fluor for further advice.

Information contained in this publication, or as otherwise supplied to the Users is believed to be accurate and given in good faith, but it is for the User to satisfy itself of the suitability for its own particular purpose. Mexichem Fluor gives no warranty as to the fitness of the Product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that such exclusion is prevented by law. Mexichem Fluor accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patent, Copyright and Design cannot be assumed. KLEA® and Mexichem Fluor® are trademarks of Mexichem SAB de C.V. Mexichem UK Limited is Registered in England No 07088219. Registered Office, The Heath Business & Technical Park, Runcorn, Cheshire, WA7 4QX.


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